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Material Safety Data Sheet: Nickel Isooctanoate

Identification

Product Name: Nickel Isooctanoate
Synonyms: Nickel 2-ethylhexanoate, Nickel octoate
Chemical Formula: C16H30NiO4
CAS Number: 27253-38-9
Recommended Use: Catalyst in chemical processes, drying agent in coatings, additive in plastics
Supplier Details: Manufacturer name and address, emergency contact, phone number
Emergency Telephone: Available 24/7 for accidental exposure or spills

Hazard Identification

Hazard Class: Acute Toxicity - Oral (Category 4), Skin Sensitizer (Category 1), Carcinogenicity (Category 2), Aquatic Chronic (Category 2)
Signal Word: Warning
Hazard Statements: May cause allergic skin reactions. Harmful if swallowed. Suspected of causing cancer. Toxic to aquatic life with long lasting effects.
Precautionary Statements: Avoid breathing dust, fume, gas, mist, vapors, or spray. Wear protective gloves, protective clothing, eye protection, and face protection. Contaminated work clothing should not be allowed out of the workplace. Wash hands thoroughly after handling. Avoid release to the environment.
Routes of Exposure: Inhalation, ingestion, skin contact, eye contact
Symptoms of Exposure: Eye or skin irritation, tingling or redness at site, sore throat or cough if inhaled, nausea, headache or dizziness if swallowed
Other Hazards: Prolonged exposure can lead to sensitization or health complications due to nickel content.

Composition / Information on Ingredients

Nickel Isooctanoate: 100%
Chemical Formula: C16H30NiO4
CAS Number: 27253-38-9
Impurities: Trace metal contaminants may be present from source materials
Stabilizers: None reported
Other Constituents: No additional active ingredients

First Aid Measures

Inhalation: Move to fresh air. Monitor breathing. Seek medical help if feeling unwell, if coughing, or if symptoms persist.
Skin Contact: Remove contaminated clothing. Wash exposed skin thoroughly with soap and water. Do not use solvents. Seek medical attention for rash or irritation.
Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. Seek immediate medical care for redness, pain, or vision changes.
Ingestion: Do not induce vomiting. Rinse mouth with water if conscious. Seek medical assistance promptly. Show this sheet to medical personnel.
Most Important Symptoms and Effects: Irritation, allergy, dermatitis, headache, nausea, respiratory distress in severe exposures.
Advice to Physicians: Treat symptomatically. Consider allergic reactions due to nickel sensitization.

Fire-Fighting Measures

Suitable Extinguishing Media: Carbon dioxide, dry chemical powder, foam, or water spray in case of large fire.
Extinguishing Media to Avoid: Direct, high-pressure water jet which may spread product.
Hazardous Combustion Products: Nickel oxides, carbon monoxide, carbon dioxide, irritating fumes.
Special Protective Equipment: Firefighters need self-contained breathing apparatus and full protective gear.
Fire Hazards: May produce dense, toxic smoke if involved in a fire. Nickel compounds present long-term health hazards.
Other Information: Containers exposed to extreme heat may burst. Prevent fire-fighting water from entering drains or waterways.

Accidental Release Measures

Personal Precautions: Keep unnecessary persons away. Avoid contact with skin, eyes, and clothing. Do not breathe vapors or mist.
Protective Equipment: Chemical-resistant gloves, goggles, face shield, and protective clothing. Respirator if ventilation is poor.
Environmental Precautions: Prevent further leakage or spillage if safe. Do not allow product to reach drains, water courses, or soil.
Methods for Cleanup: Absorb liquid with inert material (sand, earth, vermiculite) and collect in suitable containers for disposal. Ventilate spill area.
Disposal: Dispose of contaminated absorbent as hazardous waste. Clean spill site thoroughly.

Handling and Storage

Handling: Use with adequate ventilation. Wear protective equipment as described. Avoid direct contact with substance and inhalation of vapors or sprays. Do not eat, drink, or smoke when handling.
Storage Conditions: Store in tightly closed, corrosion-resistant containers in a cool, dry, well-ventilated area. Protect from moisture and incompatible materials such as strong oxidizing agents. Keep away from heat, sparks, and open flames.
Storage Life: Stable under recommended conditions for up to two years.
Other Precautions: Keep out of reach of children. Clearly label containers. Segregate from food and feed.

Exposure Controls and Personal Protection

Occupational Exposure Limits: Nickel compounds (as Ni): OSHA PEL 1 mg/m³ TWA, ACGIH TLV 0.1 mg/m³ TWA
Engineering Controls: Local exhaust ventilation, general room ventilation
Respiratory Protection: Approved respirator for hazardous substances if exposure exceeds limits or if ventilation is inadequate.
Eye Protection: Chemical safety goggles with side shields.
Skin Protection: Impervious gloves (nitrile, neoprene), lab coat or protective suit.
Hygiene Measures: Wash hands and face before breaks and after handling. Remove contaminated clothing promptly. Launder work clothes regularly.
Environmental Controls: Prevent product from entering water systems or soil.

Physical and Chemical Properties

Appearance: Green liquid
Odor: Slight characteristic odor
Odor Threshold: Not determined
pH: Not available
Melting Point / Range: Below 0°C
Boiling Point / Range: Above 200°C
Flash Point: Approximately 97°C (closed cup)
Evaporation Rate: Not determined
Flammability: Combustible under certain conditions
Vapor Pressure: Very low at room temperature
Vapor Density: Not determined
Relative Density: 1.08 – 1.13 g/cm³
Solubility: Insoluble in water, soluble in organic solvents
Partition Coefficient (n-octanol/water): Not available
Auto-Ignition Temperature: Above 200°C
Decomposition Temperature: Not established
Viscosity: Slightly viscous

Stability and Reactivity

Chemical Stability: Stable under normal conditions and recommended handling practices.
Reactivity: No hazardous reactions expected under normal use.
Conditions to Avoid: Avoid sources of ignition, excessive heat, incompatible substances.
Incompatible Materials: Strong oxidizers, strong acids, strong bases.
Hazardous Decomposition Products: Toxic metal oxides and organic fumes on burning.
Polymerization: No hazardous polymerization expected.

Toxicological Information

Acute Toxicity: LD50 (rat, oral): approx. 900 mg/kg (nickel compounds, general literature)
Skin Corrosion/Irritation: Causes skin irritation. Sensitizing on prolonged or repeated contact.
Serious Eye Damage/Irritation: Causes eye irritation. May cause redness, itching, pain.
Respiratory Sensitization: Nickel compounds linked to respiratory sensitization and asthma-like symptoms.
Carcinogenicity: Nickel and its compounds classified as possible human carcinogens (IARC Group 2B).
Mutagenicity: Not classified.
Reproductive Toxicity: No specific data.
Repeated Dose Toxicity: Chronic inhalation or prolonged skin exposure increases risk of sensitization, dermatitis, or other effects.
Other Information: Nickel allergy risk is significant for sensitive individuals.

Ecological Information

Aquatic Toxicity: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Persistence/Degradability: Not readily biodegradable.
Bioaccumulation Potential: Potential for bioaccumulation in aquatic organisms.
Mobility in Soil: Low mobility expected in soil. Insolubility in water limits spread but poses persistence concern.
Other Adverse Effects: Nickel is a regulated priority pollutant. Avoid disposal to open environments.
Environmental Precautions: Prevent release to waterways, drains, and soil. Inform relevant authorities in case of environmental contamination.

Disposal Considerations

Waste Treatment Methods: Dispose of according to local, regional, national, and international regulations.
Disposal of Product: Collection in tightly closed, labeled containers for hazardous waste facility disposal.
Disposal of Packaging: Triple rinse and offer for recycling, if available, or treat as hazardous waste.
Environmental Hazards: Do not allow runoff to sewer, surface water, or groundwater. Notify relevant authorities for accidental releases.
Other Notes: Follow best practices for hazardous waste handling and transportation. Professional disposal recommended for large quantities.

Transport Information

UN Number: 3082
UN Proper Shipping Name: Environmentally hazardous substance, liquid, n.o.s. (contains Nickel Isooctanoate)
Transport Hazard Class: 9 (Miscellaneous dangerous substances and articles)
Packing Group: III
Environmentally Hazardous: Yes
Marine Pollutant: Yes
Special Precautions: Ensure sealed, upright containers with proper hazard labeling. Transport within regulated temperature and security guidelines.
Transport in Bulk: Code applies per IMDG Code; check regulations for exact packaging and marking.

Regulatory Information

OSHA: Regulated as hazardous; nickel compounds listed as carcinogen
SARA Title III: Section 313 reporting for nickel compounds
RCRA Waste Code: D007 for nickel-containing wastes
TSCA: Listed
REACH: Nickel compounds subject to registration and restrictions within the EU
IARC: Nickel compounds Group 2B (possibly carcinogenic to humans)
Other Regional Regulations: Observe local, state, and national laws for handling and disposal. European directives classify as hazardous for health and environment.
Additional Information: Employers must train workers on hazardous nature, PPE requirements, safe handling, and environmental protection measures.